Part III, pp 215-1119. (c) For a recent review with emphasis on alkene syntheses, see: Negishi, E.; Wang, G.; Rao, H.; Xu, Z. J. Org. Chem. 2010, 75, 3151.
15. (a) Miyaura, N.; Suzuki, A. Chem. Rev. 1995, 95, 2457. (b) Suzuki, A.; Brown, H. C. Organic Syntheses via Boranes, Vol. 3: Suzuki Coupling, Aldrich Chemical Co., Milwaukee, 2003, p 314.
16. Negishi, E.; Xu, S.; Truex, N.; Rao, H.; Tobrman, T.; Mohan, S.; Gao, J.; Maishal, T. manuscript in preparation.
17. (a) Heck, R. F.; Nolley, J. P., Jr. J. Org. Chem. 1972, 37, 2320. (b) Heck, R. F. Org. React. 1982, 27, 345-390. (c) Beletskaya, I. P.; Cheprakov, A. V. In The Mizoroki-Heck Reaction; Oestreich, M., Ed.; John Wiley & Sons, Ltd.; Chichester, U. K., 2009; Chapter 2, pp 51-132. (d) Jeffery, T. Tetrahedron Lett. 1985, 26, 2667-2670. (e) Farina, V. Adv. Synth. Catal. 2004, 346, 1553. (f) Lemhadri, M.; Battace, A.; Berthiol, F.; Zair, T.; Doucet, H.; Santelli, M. Synthesis, 1142-1152. Note: Three out of >40 examples display TONs of 7000, 8100, and 9500, which represent the three highest TONs exceeding 1000 in this study (Ref. 17f).
18. (a) Van Horn, D. E.; Negishi, E. J. Am. Chem. Soc. 1978, 100, 2252. (b) Negishi, E.; Van Horn, D. E.; Yoshida, T. J. Am. Chem. Soc. 1985, 107, 6639. (c) Olah, G. A. Angew. Chem. Int. Ed. 1993, 105, 767. (d) Negishi, E. Chem. Eur. J. 1999, 5, 411.
19. (a) Kondakov, D. Y.; Negishi, E. J. Am. Chem. Soc. 1995, 117, 10771. (b) Kondakov, D. Y.; Negishi, E. J. Am. Chem. Soc. 1996, 118, 1577.
20. Dzhemilev, U. M.; Vostrikova, O. S.; Sultanov, R. M. Izv. Akad. Nauk SSSR, Ser. Khim. 1983, 218.
21. For a review, see: Negishi, E.; Kondakov, D. Y. Chem. Soc. Rev. 1996, 417.
22. Takahashi, T.; Seki, T.; Nitto, Y.; Saburi, M.; Rousset, C. J.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 6266.
23. Negishi, E.; Kondakov, D. Y.; Choueiry, D.; Kasai, K.; Takahashi, T. J. Am. Chem. Soc. 1996, 118, 9577.
24. Ott, K. C.; deBoer, E. J. M.; Grubbs, R. H. Organometallics 1984, 3, 223.
25. For a review of this subject, see: Negishi, E.; Novak, T. In Comprehensive Organometallic Chemistry III; Ojima, I., Ed.; Elsevier: Oxford, 2007; Chap. 10.06, pp 251-297.
26. (a) Morken, J. P.; Didiuk, M. T.; Hoveyda, A. H. J. Am. Chem. Soc. 1993, 115, 6997. (b) Didiuk, M. T.; Johannes, C. W.; Morken, J. P.; Hoveyda, A. H. J. Am. Chem. Soc. 1995, 117, 7097.
27. (a) Bell, L.; Whitby, R. J.; Jones, R. V. H.; Standen, M. C. H. Tetrahedron Lett. 1996, 37, 7139. (b) Yamamura, Y.; Hyakutake, M.; Mori, M. J. Am. Chem. Soc. 1997, 119, 7615.
28. For a study of zirconocene-catalyzed alkene carbomagnesiation with longer alkylmagnesium derivatives, see: Rousset, C. J.; Negishi, E.; Suzuki, N.; Takahashi, T. Tetrahedron Lett. 1992, 33, 1965.
29. (a) Erker, G.; Aulbach, M.; Knickmeier, M.; Wingbermuhle, D.; Krüger, C.; Nolte, M.; Werner, S. J. Am. Chem. Soc. 1993, 115, 4590. (b) Wild, F. R. W. P.; Zsolnai, L.; Huttner, G.; Brintzinger, H. H. J. Organomet. Chem. 1982, 232, 233. (c) Wild, F. R. W. P.;
