2-(4-Chlorophenyl)-1,2-dihydronaptho[1,2-f][1,4]oxazepin-3(4H)-one 7c. Yield: 72%. mp: 133 °C. IR (KBr) •max: 1656, 1615-1495, 1242 cm-1. UV (EtOH) •max(log •): 388.0 (0.017), 314.4 (0.065), 278.8 (0.202), 259.2 (0.997) nm. 1H-NMR (400 MHz, CDCl3) •: 4.82 (2H, s, - CH2-O), 5.20 (2H, s, -CH2-N), 7.12 (2H, d, J=8.0 Hz, 3•N•-H), 7.30 (1H, d, J=8.8 Hz, 3-H), 7.31 (2H, d, J=8.0 Hz, 2•N•-H), 7.37 (1H, t, J=8.4 Hz, 6-H), 7.48 (1H, t, J=6.8 Hz, 7-H), 7.70 (1H, d, J=8.4 Hz, 4-H), 7.79 (1H, d, J=8.4 Hz, 5-H), 7.81 (1H, d, J=7.1 Hz, 8-H). 13C-NMR (100 MHz, CDCl3) •: 47.1 (Ar-CH2-N), 73.3 (O-CH2), 120.4 (3-C), 122.2 (8-C), 122.5 (2•N•-C), 125.4 (6-C), 127.9 (7-C), 130.1 (4-C), 130.1 (5-C), 130.8 (4a-C), 131.2 (8a-C), 131.4 (3•N•-C), 133.5 (4•N•-C), 142.9 (1•N•-C), 156.5 (2-C), 169.5 (C=O). MS: m/z 323 (M+). Anal. Calcd. for C19H14ClNO2 (323.77): C, 70.48; H, 4.36; N, 4.33. Found: C, 70.31; H, 4.69; N, 4.34.
Acknowledgements
This work was supported by the Eskisehir Osmangazi University Scientific Research Project Commission (Grant No. 200419036).
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