Issue in Honor of Prof. Alexandru T. Balaban ARKIVOC 2005 (x) 254-271
Table 1. Log(RS) values of sugars/halosugars
Crt. No. Name Str. in Fig. 1 R1 R2 R3 R4 R5 Log RS Obs. Log RS Calc. Recommended for synthesis 1 Lactose -------0.699 -0.151 2 -I OH OH OH OH OH -0.699 -0.174 3 Mannose -------0.523 -0.081 no 4 Galactose -------0.495 -0.819 5 Maltose -------0.481 0.250 6 Xylose -------0.398 -0.204 7 a-Glucose -------0.155 -0.478 8 ß-Glucose -------0.097 -0.523 no 9 Sorbose -------0.066 0.242 10 -I OH H OH OH OH 0.000 0.121 11 -II --OH OH OH 0.000 -0.220 12 Fructose ------0.236 0.007 13 -I OH OH OH Cl OH 0.301 0.529 no 14 -I OH Cl OH OH OH 0.699 0.884 15 -I OH OH OH Cl Cl 0.699 1.087 16 -I OH OH Cl OH OH 1.301 0.413 17 -I OH OH OH OH Cl 1.301 1.191 18 -II --Cl OH OH 1.301 0.923 uncertain 19 -II --OH OH Cl 1.301 1.250 20 -I Cl OH Cl OH Cl 1.398 1.226 21 -I OH OH Cl Cl OH 1.477 1.287 22 -I OH F F OH F 1.602 1.579 23 -I OH Cl OH OH Cl 1.699 2.073 yes 24 -I OH OH Cl OH Cl 1.881 1.608 25 -II --Cl OH Cl 1.903 1.501 26 -II --Br OH Br 1.903 1.910 27 -I OH OH Cl Cl Cl 2.000 2.173 28 -II --Cl Cl Cl 2.000 2.050 yes 29 -I OH Cl Cl OH OH 2.079 1.717 30 -I OH Cl Cl H Cl 2.176 1.950 31 -I OH Cl OH Cl Cl 2.204 2.796 32 -I Cl Cl Cl OH Cl 2.301 2.338 33 -I OH Cl Cl Cl OH 2.342 1.498 uncertain 34 -I OH Br Cl OH Cl 2.574 2.836 35 -I H Cl Cl OH Cl 2.602 2.673 36 -I OH Cl Cl OH Cl 2.813 2.882 37 -I OH Cl Br OH Br 2.903 2.918 38 -I OH Cl Cl F Cl 3.000 2.900 yes 39 -I OH Cl Cl Cl Cl 3.477 3.062 40 -I OH Cl Cl Br Cl 3.477 3.209 41 -I OH Cl Cl I Cl 3.875 3.991
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